In an electronics manufacturing facility, a new low-temperature solder paste for reflow soldering is used. Some flux is remained on solder joints. These residues formed some noticeable white spots around the solder joints, affecting the reliability and appearance of the solder joints. In this article, we focus on 3 parts: What is flux residue? Why do flux residues occur? How to fix flux residue?
What is flux residue?
The flux residue caused by low-temperature solder paste during reflow soldering refers to the fact that the flux used in the soldering process cannot be completely volatilized or decomposed, resulting in a certain amount of flux remaining in the solder joint or soldering area.
What are the common types of flux residue?
Flux residue is a key consideration in electronics assembly and manufacturing. Understanding the different types of flux residue and their implications is essential for ensuring the reliability and quality of electronic products. Let’s delve into the most common types of flux residue, examining their characteristics, sources, effects, and management practices.
1. Rosin-Based Flux Residue
Characteristics: Rosin-based flux is derived from natural resins and is widely used in electronics due to its effectiveness in cleaning metal surfaces and preventing oxidation. The residue left behind is typically sticky and can vary in appearance from light brown to dark, depending on the flux’s formulation and the soldering conditions.
Sources: This residue results from flux that has not been fully cleaned off after the soldering process. It often remains on the circuit board or component surfaces.
Effects: Rosin flux residue is generally non-conductive but can be hygroscopic, meaning it absorbs moisture. Over time, this can potentially lead to corrosion of the underlying metal surfaces. While it might not directly impact electrical performance, it can affect long-term reliability.
Management: To manage rosin-based residue, manufacturers often use solvent-based or ultrasonic cleaning methods to remove it effectively. Ensuring thorough cleaning helps prevent potential issues related to moisture absorption and corrosion.
2. Water-Soluble Flux Residue
Characteristics: Water-soluble fluxes are designed to be cleaned off with water after soldering. They are often formulated to leave minimal residue, but the residues that do remain can be more prone to attracting moisture and may be slightly more corrosive than rosin-based residues.
Sources: Residue from water-soluble flux comes from fluxes that are intended to be washed away after soldering. If the cleaning process is incomplete, residues can remain on the circuit board.
Effects: The primary concern with water-soluble flux residue is its potential to attract moisture, which can lead to corrosion and reliability issues. It may also cause conductive pathways or degrade the performance of the electronic assembly if left unchecked.
Management: Proper cleaning is crucial when using water-soluble flux. This typically involves rinsing the circuit board with deionized water and then drying it thoroughly to prevent any remaining residue from causing issues. Ultrasonic cleaning is also a popular method for effectively removing these residues.
3. No-Clean Flux Residue
Characteristics: No-clean fluxes are designed to leave minimal residue that doesn’t require post-soldering cleaning. The residue is usually a thin, non-conductive film that is generally considered safe for most applications.
Sources: Residue from no-clean flux is an intentional byproduct, as these fluxes are formulated to leave behind a small amount of residue that is deemed non-harmful.
Effects: Although no-clean residues are not typically corrosive or conductive, they can sometimes cause visual defects or leave a haze on the board. In critical applications, even these minimal residues might need to be inspected to ensure they don’t affect performance.
Management: For most cases, no-clean flux residues do not require cleaning. However, visual inspection and functional testing are important to ensure that the residue does not affect the assembly’s performance. In certain high-reliability applications, further cleaning might be required to meet stringent standards.
4. General Considerations
Inspection: Regardless of the type of flux residue, inspecting the finished assembly is essential. Techniques like visual inspection, X-ray imaging, and electrical testing can help identify any issues related to flux residue.
Standards: Adhering to industry standards and guidelines, such as IPC (Institute of Printed Circuits) standards, helps ensure that flux residues are managed appropriately and do not impact product quality.
Each type of flux residue—rosin-based, water-soluble, and no-clean—has its own set of characteristics, sources, and potential effects on electronic assemblies. Understanding these aspects helps in implementing appropriate cleaning and inspection processes, ultimately ensuring the reliability and performance of electronic products. By paying careful attention to these details,can effectively manage flux residues and maintain high standards of quality in their products.
Chemical properties of solder and flux residue
The chemical properties of solder and flux residue significantly impact electronics, with solder typically consisting of a blend of tin and lead (or other alloys like tin-silver-copper) that forms a strong, conductive joint when melted, while flux residues—originating from rosin, water-soluble, or no-clean fluxes—have varying effects; rosin residues are mildly acidic and can absorb moisture, potentially leading to corrosion, while water-soluble flux residues are more prone to causing corrosion if not cleaned thoroughly, and no-clean flux residues, though minimal and generally non-corrosive, might still affect the aesthetic or performance of sensitive components.
What are the possible effects?
1.Electrical performance issues
Flux residues can negatively affect the electrical performance of solder joints and circuit boards. Besides, it can cause shorts or poor conduction between circuit boards as well, affecting the proper function of the circuit. In addition, the stability and reliability of solder joints might also be impacted, leading to increased resistance or failure of solder joints.
2. Reliability issues
The reliability of solder connections can be greatly affected. Flux residues may cause corrosion of solder joints, metal ion migration or oxidation, thereby reducing the reliability of solder joints. This leads to cracking of solder joints, loosening or failure under high temperature or vibration conditions.
3.Difficulty in cleaning
If the flux residue is difficult to remove, it may not only increase the complexity and difficulty of the cleaning process, but also adversely affect subsequent process steps, such as coating, packaging or testing. In addition, the residues may also reduce the surface adhesion after cleaning, affecting the quality of subsequent coating or bonding.
Also read: What’s the type of PCB surface treatment?
4.Appearance and visibility issues
Flux residue may leave unclean marks or bubbles on the soldering surface. This may affect the appearance quality of the product and reduce the visibility of solder joints. In some applications, appearance and visibility are important factors, so flux residue may be considered a quality issue.
Why do flux residues occur?
Here are some factors that can cause flux residue:
1.Incompatible flux ingredients
Low-temperature solder paste usually suits a lower temperature soldering process, while traditional high-temperature solder may contain flux ingredients that are difficult to completely volatilize or decompose during low-temperature soldering.
Therefore, it is critical to choose a flux that is compatible with low-temperature solder pastes to ensure proper volatilization or decomposition of the flux during reflow.
2. Improper temperature control
Low-temperature solder paste needs to be reflowed in a suitable temperature range to ensure the quality of solder joints and the complete volatilization of flux. If the reflow temperature is too high or too low, the flux may not evaporate completely or decompose, resulting in the formation of residues.
3.Mismatched material or quality problems
Quality problems of low-temperature solder paste, flux, or other related materials may also cause flux residues. For example, if the selected low-temperature solder paste is not compatible with the flux used, or there are quality problems in the material itself, it may cause the flux to not completely volatilize or decompose.
How to fix flux residue?

After we have learned the resons of flux residue result from the low-temperature solder paste. There are some measures can be employed to fix the flux residue issue.
1.Control reflow soldering parameters
Correctly control the temperature and time parameters of reflow soldering to ensure that the flux can be fully volatilized and decomposed. Too high a temperature may cause incomplete volatilization of the flux, while too low a temperature may not melt and decompose the flux. Adjust the temperature curve and time of the reflow oven according to the requirements of low-temperature solder paste and flux.
2. Optimize the cleaning process
Thoroughly clean the soldered PCB to remove flux residues. Choose an appropriate cleaning agent and cleaning method to ensure that the cleaning agent can effectively remove the flux and have good compatibility with PCBs and components. For solder joints or local residues that are difficult to clean, ultrasonic cleaning or other special cleaning techniques can be considered to solve it.
Also read: How to maintain and clean PCB stencils for consistent performance?
3.Improve quality control and inspection
Strengthening the quality control process to ensure the correct application of low-temperature solder paste and the stability of the soldering process. Use appropriate inspection methods and tools, such as x-ray inspection or microscopy, to identify flux residue issues and correct them as soon as possible.
Also read: Four PCBA inspection items you need to know
4.Strengthen supply chain management
Cooperating with suppliers to ensure that the purchased low-temperature solder paste and flux meet the requirements and have quality and reliability guarantees. Establish a sound supply chain management system to ensure the stable supply and quality consistency of raw materials.
5.Training and technical support
Training our operators to understand the characteristics of low-temperature solder paste and flux and the correct use methods. Work with your supplier or professional technical support personnel for technical support and advice to resolve flux residue issues.
6.Select the appropriate low-temperature solder paste and flux
Ensure that the selected low-temperature solder paste and flux are compatible with each other, and the flux has good volatility and decomposition. Choose proven products and ensure they meet welding requirements and standards.
How to deal with PCB flux residue
Dealing with flux residue on printed circuit boards (PCBs) is essential for maintaining the reliability and performance of electronic assemblies.
1. Understanding Flux Residue
Flux residue remains on PCBs after the soldering process. It can vary depending on the type of flux used—rosin-based, water-soluble, or no-clean. Each type of residue has distinct characteristics and implications for the PCB’s performance and longevity.
2. Identifying the Type of Flux Residue
Rosin-Based Flux: Leaves a sticky, often brownish residue that can absorb moisture over time. It is generally non-conductive but can be mildly acidic. Water-Soluble Flux: Creates residues that are more easily cleaned but can be more corrosive if left on the board. No-Clean Flux: Produces minimal residue that does not typically require cleaning but might still be inspected for visual defects.
3. Cleaning Processes
1. Solvent Cleaning: Use solvent-based cleaners specifically designed for the type of flux residue present. These cleaners dissolve and remove residues without damaging the PCB or components. Common solvents include isopropyl alcohol or specialized flux removers.
2. Ultrasonic Cleaning: This method uses high-frequency sound waves to agitate a cleaning solution, effectively removing residues from complex board geometries and tight spaces. It’s particularly useful for water-soluble flux residues.
3. Manual Scrubbing: For areas where residues are stubborn or hard to reach, gentle brushing with a soft-bristled brush and a cleaning solution can be effective. This method requires careful handling to avoid damaging the PCB.
4. Water Rinsing: After using water-soluble flux, rinsing the PCB with deionized water helps remove any remaining residues. It’s important to ensure thorough drying to prevent moisture-related issues.
4. Inspection and Testing
1. Visual Inspection: Use magnification tools or microscopes to check for any remaining flux residue or visual defects. This helps ensure that the cleaning process has been effective.
2. Electrical Testing: Perform electrical tests to ensure that no conductive residues are present that could impact the circuit’s functionality. This step is crucial for high-reliability applications.
3. Functional Testing: Verify that the assembled PCB functions as intended. Functional testing can help identify any issues that might arise from residual flux or improper cleaning.
5. Prevention and Best Practices
1. Choose the Right Flux: Selecting a flux that suits your application and cleaning capabilities can minimize residue issues. No-clean fluxes, for instance, reduce the need for extensive cleaning but may still require inspection.
2. Implement Cleaning Protocols: Develop and follow standard operating procedures for cleaning to ensure consistency and effectiveness. Regularly review and update these protocols based on new materials or technologies.
3. Maintain Equipment: Ensure that cleaning equipment such as ultrasonic baths and solvent dispensers are well-maintained and calibrated. This helps achieve optimal cleaning results.
Effectively managing PCB flux residue involves understanding the type of flux used, employing appropriate cleaning methods, and conducting thorough inspections and testing. By following these practices, you can ensure that your PCBs are free of residues that could compromise performance, reliability, or aesthetics. Implementing these strategies will help maintain high standards in electronic assembly and manufacturing.
Conclusion
Flux residue is one of common defects occurred in reflow soldering. The above six measures can be some recommending suggestions for you to solve this problem. We can found that the quality and compatibility between the solder paste and the flux are essential to avoid the flux residue. Thus, select appropriate solder paste and flux is critical.
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The flux residue caused by low-temperature solder paste during reflow soldering refers to the fact that the flux used in the soldering process cannot be completely volatilized or decomposed, resulting in a certain amount of flux remaining in the solder joint or soldering area.
- Electrical performance issues
- Reliability issues
- Difficulty in cleaning
- Appearance and visibility issues
- Control reflow soldering parameters
- Optimize the cleaning process
- Improve quality control and inspection
- Strengthen supply chain management
- Training and technical support
- Select the appropriate low-temperature solder paste and flux
Flux residue can pose problems in electronics because it may lead to corrosion, affect electrical performance, or create reliability issues if not properly managed; rosin-based residues might absorb moisture and potentially cause long-term corrosion, water-soluble residues can attract moisture and lead to conductive paths if not fully cleaned, and even no-clean residues, though minimal, can sometimes cause aesthetic issues or interfere with sensitive components, highlighting the importance of effective cleaning and inspection processes to ensure the longevity and functionality of electronic assemblies.
To reduce flux residue, start by choosing the appropriate type of flux for your application, such as no-clean flux, which leaves minimal residue, or using water-soluble flux with a strong cleaning protocol; ensure thorough cleaning after soldering by employing methods like ultrasonic cleaning or solvent washing to remove any remaining residue; and implement effective drying techniques to prevent moisture-related issues. Additionally, maintaining well-calibrated cleaning equipment and adhering to stringent cleaning standards can further minimize residue, ultimately enhancing the performance and reliability of your electronic assemblies.
Flux content refers to the chemical composition of the flux used in soldering, which typically includes a blend of active chemicals like rosin or organic acids, along with solvents and other additives designed to clean metal surfaces, prevent oxidation, and ensure proper solder flow; the specific components of flux content can vary depending on whether it's a rosin-based, water-soluble, or no-clean flux, each affecting the soldering process and residue left behind in different ways.
Last updated on September 6th, 2024 at 06:01 am





